Mohr method – determination of chlorides by titration with silver nitrate. The determination of silver or halides by the precipitation of the silver salts is known as argentometric titrations. Here titrant forms precipitate. The dispensed chloride plug is analyzed quantitatively by argentometric titration. If the titration can be performed with high enough precision, the autosampler.

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One of the earliest precipitation titrations—developed at the end of the eighteenth century—was the analysis of K 2 CO 3 and K 2 SO 4 in potash.


A second type of indicator uses a species that forms a colored complex with the titrant or the titrand. Quantitative Calculations The argentometrric relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction.

Carbonates and phosphates precipitate titratino silver, and need to be absent to prevent inaccurate results. The red points corresponds to the data in Table 9. About us Feedback Mohr method – determination of chlorides by titration with silver nitrate. Chloride ions react with silver I ions to give the insoluble silver chloride:.

We call this type of titration a precipitation titration.

After the equivalence point, the titrant is in excess. By now you are familiar with our approach to calculating a titration curve. Note See Table 9.


Precipitation Titrations – Chemistry LibreTexts

In the Fajans method, named after Kazimierz Fajanstypically dichlorofluorescein is used as an indicator; the end-point is argentimetric by the green suspension turning pink. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains in solution where it has a greenish-yellow color. Waylander 5, 1 10 As we have done with other titrations, we first show how to calculate the titration curve and then demonstrate how we can quickly sketch a reasonable approximation of the titration curve.

Because CrO 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of K 2 CrO 4 is added.

Argentometry – Wikipedia

The analysis for I — using the Volhard method requires a back titration. To calculate the concentration of Cl — we use the K sp expression for AgCl; thus. Prior to the end-point of the titration, chloride ions remain in excess. All chlorides are dissolved out of the residue, and titrated.

Our goal is to sketch the titration curve quickly, using as few calculations as possible. In low pH silver chromate solubility grows due to the protonation of chromate anions, argentommetric high pH silver starts to react with hydroxide anions, precipitating in form of AgOH and Ag 2 O. Post as a guest Name. To calculate chlorides solution concentration use EBAS – stoichiometry calculator.


They are most often used for determination of chloride ions, but they can be used also for other argentomettric bromide, iodide and some pseudohalides thiocyanate. Analytical Chemistry for Technicians. As a result, the end point is always later than the equivalence point. Typically, it is used to determine the amount of chloride present in a sample. The sample solution is titrated against a solution of silver nitrate of known concentration.

Calculate pCl after the equivalence point by first calculating the concentration of excess AgNO 3 and then argentojetric the concentration of Cl — using the K sp for AgCl. They adsorb on the AgCl surface, imparting a negative charge to the particles.

In the Mohr method, named after Karl Friedrich Mohrpotassium chromate is an indicator, giving red silver chromate after all chloride ions have reacted:. In analytical chemistryargentometry is a type of titration involving the silver I ion.

The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction. Views Read Edit View history. Argentomettic is relatively easy titration, with no other problems then those listed on general sources of titration errors page.